Periodic table and its characteristic
The periodic table, or periodic table of elements, is a tabular arrangement of the chemical elements, ordered by their atomic number, electron configuration, and recurring chemical properties, whose structure shows periodic trends. Generally, within one row (period) the elements are metals to the left, and non-metals to the right, with the elements having similar chemical behaviours placed in the same column. Table rows are commonly called periods and columns are called groups. Six groups have accepted names as well as assigned numbers: for example, group 17 elements are the halogens; and group 18 are the noble gases. Also displayed are four simple rectangular areas or blocks associated with the filling of different atomic orbitals.
The organization of the periodic table can be used to derive relationships between the various element properties, but also the predicted chemical properties and behaviours of undiscovered or newly synthesized elements. Russian chemist Dmitri Mendeleevwas the first to publish a recognizable periodic table in 1869, developed mainly to illustrate periodic trends of the then-known elements. He also predicted some properties of unidentified elements that were expected to fill gaps within the table. Most of his forecasts proved to be correct. Mendeleev's idea has been slowly expanded and refined with the discovery or synthesis of further new elements and the development of new theoretical models to explain chemical behaviour. The modern periodic table now provides a useful framework for analyzing chemical reactions, and continues to be widely used in chemistry, nuclear physics and other sciences.
All the elements from atomic numbers 1 (hydrogen) through 118 (oganesson) have been either discovered or synthesized, completing the first seven rows of the periodic table.[1][2] The first 98 elements exist in nature, although some are found only in trace amounts and others were synthesized in laboratories before being found in nature.[n 1]Elements 99 to 118 have only been synthesized in laboratories or nuclear reactors.[3] The synthesis of elements having higher atomic numbers is currently being pursued: these elements would begin an eighth row, and theoretical work has been done to suggest possible candidates for this extension. Numerous synthetic radionuclidesof naturally occurring elements have also been produced in laboratories.
Grouping methods
Groups
A group or family is a vertical column in the periodic table. Groups usually have more significant periodic trends than periods and blocks, explained below. Modern quantum mechanical theories of atomic structure explain group trends by proposing that elements within the same group generally have the same electron configurations in their valence shell.[13] Consequently, elements in the same group tend to have a shared chemistry and exhibit a clear trend in properties with increasing atomic number.[14]In some parts of the periodic table, such as the d-block and the f-block, horizontal similarities can be as important as, or more pronounced than, vertical similarities.[15][16][17]
Under an international naming convention, the groups are numbered numerically from 1 to 18 from the leftmost column (the alkali metals) to the rightmost column (the noble gases).[18] Previously, they were known by roman numerals. In America, the roman numerals were followed by either an "A" if the group was in the s- or p-block, or a "B" if the group was in the d-block. The roman numerals used correspond to the last digit of today's naming convention (e.g. the group 4 elements were group IVB, and the group 14 elements were group IVA). In Europe, the lettering was similar, except that "A" was used if the group was before group 10, and "B" was used for groups including and after group 10. In addition, groups 8, 9 and 10 used to be treated as one triple-sized group, known collectively in both notations as group VIII. In 1988, the new IUPAC naming system was put into use, and the old group names were deprecated.[19]
Some of these groups have been given trivial (unsystematic) names, as seen in the table below, although some are rarely used. Groups 3–10 have no trivial names and are referred to simply by their group numbers or by the name of the first member of their group (such as "the scandium group" for group 3),[18] since they display fewer similarities and/or vertical trends.
Elements in the same group tend to show patterns in atomic radius, ionization energy, and electronegativity. From top to bottom in a group, the atomic radii of the elements increase. Since there are more filled energy levels, valence electrons are found farther from the nucleus. From the top, each successive element has a lower ionization energy because it is easier to remove an electron since the atoms are less tightly bound. Similarly, a group has a top-to-bottom decrease in electronegativity due to an increasing distance between valence electrons and the nucleus.[20] There are exceptions to these trends: for example, in group 11, electronegativity increases farther down the group.[21]
Groups in the Periodic table
| IUPAC group | 1 | 2 | 3a | a | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Mendeleev(I–VIII) | I | II | III | IV | V | VI | VII | VIII | I | II | III | IV | V | VI | VII | b | ||||
| CAS(US, A-B-A) | IA | IIA | IIIB | IVB | VB | VIB | VIIB | VIIIB | IB | IIB | IIIA | IVA | VA | VIA | VIIA | VIIIA | ||||
| old IUPAC(Europe, A-B) | IA | IIA | IIIA | IVA | VA | VIA | VIIA | VIII | IB | IIB | IIIB | IVB | VB | VIB | VIIB | 0 | ||||
| Trivial name | Alkali metals | Alkaline earth metalsr | Coinage metals | Triels | Tetrels | Pnictogensr | Chalcogensr | Halogensr | Noble gasesr | |||||||||||
| Name by elementr | Lithium group | Beryllium group | Scandium group | Titanium group | Vanadium group | Chromium group | Manganese group | Iron group | Cobalt group | Nickel group | Copper group | Zinc group | Boron group | Carbon group | Nitrogen group | Oxygen group | Fluorine group | Helium orNeon group | ||
| Period 1 | H h | He | ||||||||||||||||||
| Period 2 | Li | Be | B | C | N | O | F | Ne | ||||||||||||
| Period 3 | Na | Mg | Al | Si | P | S | Cl | Ar | ||||||||||||
| Period 4 | K | Ca | Sc | Ti | V | Cr | Mn | Fe | Co | Ni | Cu | Zn | Ga | Ge | As | Se | Br | Kr | ||
| Period 5 | Rb | Sr | Y | Zr | Nb | Mo | Tc | Ru | Rh | Pd | Ag | Cd | In | Sn | Sb | Te | I | Xe | ||
| Period 6 | Cs | Ba | La | Ce–Lu | Hf | Ta | W | Re | Os | Ir | Pt | Au | Hg | Tl | Pb | Bi | Po | At | Rn | |
| Period 7 | Fr | Ra | Ac | Th–Lr | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |
a Group 3 has scandium (Sc) and yttrium (Y). For the rest of the group, sources differ as either being (1) lutetium (Lu) and lawrencium (Lr), or(2) lanthanum (La) and actinium (Ac), or(3) the whole set of 15+15 lanthanides and actinides.IUPAC has initiated a project to standardize the definition as either (1) Sc, Y, La and Ac, or (2) Sc, Y, Lu and Lr.[22]
b Group 18, the noble gases, were not discovered at the time of Mendeleev's original table. Later (1902), Mendeleev accepted the evidence for their existence, and they could be placed in a new "group 0", consistently and without breaking the periodic table principle.
r Group name as recommended by IUPAC.
h Hydrogen (H), while placed in group 1, is not considered to be part of the alkali metals.
b Group 18, the noble gases, were not discovered at the time of Mendeleev's original table. Later (1902), Mendeleev accepted the evidence for their existence, and they could be placed in a new "group 0", consistently and without breaking the periodic table principle.
r Group name as recommended by IUPAC.
h Hydrogen (H), while placed in group 1, is not considered to be part of the alkali metals.
Periods
A period is a horizontal row in the periodic table. Although groups generally have more significant periodic trends, there are regions where horizontal trends are more significant than vertical group trends, such as the f-block, where the lanthanides and actinides form two substantial horizontal series of elements.[23]
Elements in the same period show trends in atomic radius, ionization energy, electron affinity, and electronegativity. Moving left to right across a period, atomic radius usually decreases. This occurs because each successive element has an added proton and electron, which causes the electron to be drawn closer to the nucleus.[24] This decrease in atomic radius also causes the ionization energy to increase when moving from left to right across a period. The more tightly bound an element is, the more energy is required to remove an electron. Electronegativity increases in the same manner as ionization energy because of the pull exerted on the electrons by the nucleus.[20] Electron affinity also shows a slight trend across a period. Metals (left side of a period) generally have a lower electron affinity than nonmetals (right side of a period), with the exception of the noble gases.[25]
Blocks
.svg)
Left to right: s-, f-, d-, p-block in the periodic table
Specific regions of the periodic table can be referred to as blocks in recognition of the sequence in which the electron shells of the elements are filled. Each block is named according to the subshell in which the "last" electron notionally resides.[26][n 3] The s-blockcomprises the first two groups (alkali metals and alkaline earth metals) as well as hydrogen and helium. The p-block comprises the last six groups, which are groups 13 to 18 in IUPAC group numbering (3A to 8A in American group numbering) and contains, among other elements, all of the metalloids. The d-block comprises groups 3 to 12 (or 3B to 2B in American group numbering) and contains all of the transition metals. The f-block, often offset below the rest of the periodic table, has no group numbers and comprises lanthanides and actinides.[27]
Metals, metalloids and nonmetals
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Metals, metalloids, nonmetals, and elements with unknown chemical properties in the periodic table. Sources disagree on the classification of some of these elements.
According to their shared physical and chemical properties, the elements can be classified into the major categories of metals, metalloids and nonmetals. Metals are generally shiny, highly conducting solids that form alloys with one another and salt-like ionic compounds with nonmetals (other than noble gases). A majority of nonmetals are coloured or colourless insulating gases; nonmetals that form compounds with other nonmetals feature covalent bonding. In between metals and nonmetals are metalloids, which have intermediate or mixed properties.[28]
Metal and nonmetals can be further classified into subcategories that show a gradation from metallic to non-metallic properties, when going left to right in the rows. The metals may be subdivided into the highly reactive alkali metals, through the less reactive alkaline earth metals, lanthanides and actinides, via the archetypal transition metals, and ending in the physically and chemically weak post-transition metals. Nonmetals may be simply subdivided into the polyatomic nonmetals, being nearer to the metalloids and show some incipient metallic character; the essentially nonmetallic diatomic nonmetals, nonmetallic and the almost completely inert, monatomic noble gases. Specialized groupings such as refractory metals and noble metals, are examples of subsets of transition metals, also known[29] and occasionally denoted.[30]
Placing elements into categories and subcategories based just on shared properties is imperfect. There is a large disparity of properties within each category with notable overlaps at the boundaries, as is the case with most classification schemes.[31]Beryllium, for example, is classified as an alkaline earth metal although its amphotericchemistry and tendency to mostly form covalent compounds are both attributes of a chemically weak or post-transition metal. Radon is classified as a nonmetallic noble gas yet has some cationic chemistry that is characteristic of metals. Other classification schemes are possible such as the division of the elements into mineralogical occurrence categories, or crystalline structures. Categorizing the elements in this fashion dates back to at least 1869 when Hinrichs[32]wrote that simple boundary lines could be placed on the periodic table to show elements having shared properties, such as metals, nonmetals, or gaseous elements.
Periodic trends and patterns
Electron configuration
Approximate order in which shells and subshells are arranged by increasing energy according to the Madelung rule
The electron configuration or organisation of electrons orbiting neutral atoms shows a recurring pattern or periodicity. The electrons occupy a series of electron shells (numbered 1, 2, and so on). Each shell consists of one or more subshells (named s, p, d, f and g). As atomic number increases, electrons progressively fill these shells and subshells more or less according to the Madelung ruleor energy ordering rule, as shown in the diagram. The electron configuration for neon, for example, is 1s2 2s2 2p6. With an atomic number of ten, neon has two electrons in the first shell, and eight electrons in the second shell; there are two electrons in the s subshell and six in the p subshell. In periodic table terms, the first time an electron occupies a new shell corresponds to the start of each new period, these positions being occupied by hydrogen and the alkali metals.[33][34]
Periodic table trends (arrows show an increase)
Since the properties of an element are mostly determined by its electron configuration, the properties of the elements likewise show recurring patterns or periodic behaviour, some examples of which are shown in the diagrams below for atomic radii, ionization energy and electron affinity. It is this periodicity of properties, manifestations of which were noticed well before the underlying theory was developed, that led to the establishment of the periodic law (the properties of the elements recur at varying intervals) and the formulation of the first periodic tables.[33][34]
Approximate order in which shells and subshells are arranged by increasing energy according to the Madelung rule
The electron configuration or organisation of electrons orbiting neutral atoms shows a recurring pattern or periodicity. The electrons occupy a series of electron shells (numbered 1, 2, and so on). Each shell consists of one or more subshells (named s, p, d, f and g). As atomic number increases, electrons progressively fill these shells and subshells more or less according to the Madelung ruleor energy ordering rule, as shown in the diagram. The electron configuration for neon, for example, is 1s2 2s2 2p6. With an atomic number of ten, neon has two electrons in the first shell, and eight electrons in the second shell; there are two electrons in the s subshell and six in the p subshell. In periodic table terms, the first time an electron occupies a new shell corresponds to the start of each new period, these positions being occupied by hydrogen and the alkali metals.[33][34]
Periodic table trends (arrows show an increase)
Since the properties of an element are mostly determined by its electron configuration, the properties of the elements likewise show recurring patterns or periodic behaviour, some examples of which are shown in the diagrams below for atomic radii, ionization energy and electron affinity. It is this periodicity of properties, manifestations of which were noticed well before the underlying theory was developed, that led to the establishment of the periodic law (the properties of the elements recur at varying intervals) and the formulation of the first periodic tables.[33][34]
Atomic radii
Atomic radii vary in a predictable and explainable manner across the periodic table. For instance, the radii generally decrease along each period of the table, from the alkali metals to the noble gases; and increase down each group. The radius increases sharply between the noble gas at the end of each period and the alkali metal at the beginning of the next period. These trends of the atomic radii (and of various other chemical and physical properties of the elements) can be explained by the electron shell theory of the atom; they provided important evidence for the development and confirmation of quantum theory.[35]
The electrons in the 4f-subshell, which is progressively filled across the lanthanideseries, are not particularly effective at shielding the increasing nuclear charge from the sub-shells further out. The elements immediately following the lanthanides have atomic radii that are smaller than would be expected and that are almost identical to the atomic radii of the elements immediately above them.[36] Hence hafnium has virtually the same atomic radius (and chemistry) as zirconium, and tantalum has an atomic radius similar to niobium, and so forth. This is known as the lanthanide contraction. The effect of the lanthanide contraction is noticeable up to platinum (element 78), after which it is masked by a relativistic effect known as the inert pair effect.[37] The d-block contraction, which is a similar effect between the d-blockand p-block, is less pronounced than the lanthanide contraction but arises from a similar cause.[36]
Atomic radii vary in a predictable and explainable manner across the periodic table. For instance, the radii generally decrease along each period of the table, from the alkali metals to the noble gases; and increase down each group. The radius increases sharply between the noble gas at the end of each period and the alkali metal at the beginning of the next period. These trends of the atomic radii (and of various other chemical and physical properties of the elements) can be explained by the electron shell theory of the atom; they provided important evidence for the development and confirmation of quantum theory.[35]
The electrons in the 4f-subshell, which is progressively filled across the lanthanideseries, are not particularly effective at shielding the increasing nuclear charge from the sub-shells further out. The elements immediately following the lanthanides have atomic radii that are smaller than would be expected and that are almost identical to the atomic radii of the elements immediately above them.[36] Hence hafnium has virtually the same atomic radius (and chemistry) as zirconium, and tantalum has an atomic radius similar to niobium, and so forth. This is known as the lanthanide contraction. The effect of the lanthanide contraction is noticeable up to platinum (element 78), after which it is masked by a relativistic effect known as the inert pair effect.[37] The d-block contraction, which is a similar effect between the d-blockand p-block, is less pronounced than the lanthanide contraction but arises from a similar cause.[36]
Ionization energy
Ionization energy: each period begins at a minimum for the alkali metals, and ends at a maximum for the noble gases
The first ionization energy is the energy it takes to remove one electron from an atom, the second ionization energy is the energy it takes to remove a second electron from the atom, and so on. For a given atom, successive ionization energies increase with the degree of ionization. For magnesium as an example, the first ionization energy is 738 kJ/mol and the second is 1450 kJ/mol. Electrons in the closer orbitals experience greater forces of electrostatic attraction; thus, their removal requires increasingly more energy. Ionization energy becomes greater up and to the right of the periodic table.[37]
Large jumps in the successive molar ionization energies occur when removing an electron from a noble gas (complete electron shell) configuration. For magnesium again, the first two molar ionization energies of magnesium given above correspond to removing the two 3s electrons, and the third ionization energy is a much larger 7730 kJ/mol, for the removal of a 2p electron from the very stable neon-like configuration of Mg2+. Similar jumps occur in the ionization energies of other third-row atoms.[37]
Ionization energy: each period begins at a minimum for the alkali metals, and ends at a maximum for the noble gases
The first ionization energy is the energy it takes to remove one electron from an atom, the second ionization energy is the energy it takes to remove a second electron from the atom, and so on. For a given atom, successive ionization energies increase with the degree of ionization. For magnesium as an example, the first ionization energy is 738 kJ/mol and the second is 1450 kJ/mol. Electrons in the closer orbitals experience greater forces of electrostatic attraction; thus, their removal requires increasingly more energy. Ionization energy becomes greater up and to the right of the periodic table.[37]
Large jumps in the successive molar ionization energies occur when removing an electron from a noble gas (complete electron shell) configuration. For magnesium again, the first two molar ionization energies of magnesium given above correspond to removing the two 3s electrons, and the third ionization energy is a much larger 7730 kJ/mol, for the removal of a 2p electron from the very stable neon-like configuration of Mg2+. Similar jumps occur in the ionization energies of other third-row atoms.[37]
Electronegativity
Graph showing increasing electronegativity with growing number of selected groups
Electronegativity is the tendency of an atomto attract a shared pair of electrons.[38] An atom's electronegativity is affected by both its atomic number and the distance between the valence electrons and the nucleus. The higher its electronegativity, the more an element attracts electrons. It was first proposed by Linus Pauling in 1932.[39] In general, electronegativity increases on passing from left to right along a period, and decreases on descending a group. Hence, fluorine is the most electronegative of the elements,[n 5]while caesium is the least, at least of those elements for which substantial data is available.[21]
There are some exceptions to this general rule. Gallium and germanium have higher electronegativities than aluminium and siliconrespectively because of the d-block contraction. Elements of the fourth period immediately after the first row of the transition metals have unusually small atomic radii because the 3d-electrons are not effective at shielding the increased nuclear charge, and smaller atomic size correlates with higher electronegativity.[21] The anomalously high electronegativity of lead, particularly when compared to thallium and bismuth, appears to be an artifact of data selection and data availability. Methods of calculation other than the Pauling method show the normal periodic trends for these elements.[40]
Graph showing increasing electronegativity with growing number of selected groups
Electronegativity is the tendency of an atomto attract a shared pair of electrons.[38] An atom's electronegativity is affected by both its atomic number and the distance between the valence electrons and the nucleus. The higher its electronegativity, the more an element attracts electrons. It was first proposed by Linus Pauling in 1932.[39] In general, electronegativity increases on passing from left to right along a period, and decreases on descending a group. Hence, fluorine is the most electronegative of the elements,[n 5]while caesium is the least, at least of those elements for which substantial data is available.[21]
There are some exceptions to this general rule. Gallium and germanium have higher electronegativities than aluminium and siliconrespectively because of the d-block contraction. Elements of the fourth period immediately after the first row of the transition metals have unusually small atomic radii because the 3d-electrons are not effective at shielding the increased nuclear charge, and smaller atomic size correlates with higher electronegativity.[21] The anomalously high electronegativity of lead, particularly when compared to thallium and bismuth, appears to be an artifact of data selection and data availability. Methods of calculation other than the Pauling method show the normal periodic trends for these elements.[40]
Electron affinity
Dependence of electron affinity on atomic number.[41]Values generally increase across each period, culminating with the halogens before decreasing precipitously with the noble gases. Examples of localized peaks seen in hydrogen, the alkali metals and the group 11 elements are caused by a tendency to complete the s-shell (with the 6s shell of gold being further stabilized by relativistic effects and the presence of a filled 4f sub shell). Examples of localized troughs seen in the alkaline earth metals, and nitrogen, phosphorus, manganese and rhenium are caused by filled s-shells, or half-filled p- or d-shells.[42]
The electron affinity of an atom is the amount of energy released when an electron is added to a neutral atom to form a negative ion. Although electron affinity varies greatly, some patterns emerge. Generally, nonmetals have more positive electron affinity values than metals. Chlorine most strongly attracts an extra electron. The electron affinities of the noble gases have not been measured conclusively, so they may or may not have slightly negative values.[43]
Electron affinity generally increases across a period. This is caused by the filling of the valence shell of the atom; a group 17 atom releases more energy than a group 1 atom on gaining an electron because it obtains a filled valence shell and is therefore more stable.[43]
A trend of decreasing electron affinity going down groups would be expected. The additional electron will be entering an orbital farther away from the nucleus. As such this electron would be less attracted to the nucleus and would release less energy when added. In going down a group, around one-third of elements are anomalous, with heavier elements having higher electron affinities than their next lighter congenors. Largely, this is due to the poor shielding by d and f electrons. A uniform decrease in electron affinity only applies to group 1 atoms.[44]
Dependence of electron affinity on atomic number.[41]Values generally increase across each period, culminating with the halogens before decreasing precipitously with the noble gases. Examples of localized peaks seen in hydrogen, the alkali metals and the group 11 elements are caused by a tendency to complete the s-shell (with the 6s shell of gold being further stabilized by relativistic effects and the presence of a filled 4f sub shell). Examples of localized troughs seen in the alkaline earth metals, and nitrogen, phosphorus, manganese and rhenium are caused by filled s-shells, or half-filled p- or d-shells.[42]
The electron affinity of an atom is the amount of energy released when an electron is added to a neutral atom to form a negative ion. Although electron affinity varies greatly, some patterns emerge. Generally, nonmetals have more positive electron affinity values than metals. Chlorine most strongly attracts an extra electron. The electron affinities of the noble gases have not been measured conclusively, so they may or may not have slightly negative values.[43]
Electron affinity generally increases across a period. This is caused by the filling of the valence shell of the atom; a group 17 atom releases more energy than a group 1 atom on gaining an electron because it obtains a filled valence shell and is therefore more stable.[43]
A trend of decreasing electron affinity going down groups would be expected. The additional electron will be entering an orbital farther away from the nucleus. As such this electron would be less attracted to the nucleus and would release less energy when added. In going down a group, around one-third of elements are anomalous, with heavier elements having higher electron affinities than their next lighter congenors. Largely, this is due to the poor shielding by d and f electrons. A uniform decrease in electron affinity only applies to group 1 atoms.[44]
Metallic character
The lower the values of ionization energy, electronegativity and electron affinity, the more metallic character the element has. Conversely, nonmetallic character increases with higher values of these properties.[45]Given the periodic trends of these three properties, metallic character tends to decrease going across a period (or row) and, with some irregularities (mostly) due to poor screening of the nucleus by d and f electrons, and relativistic effects,[46] tends to increase going down a group (or column or family). Thus, the most metallic elements (such as caesium and francium) are found at the bottom left of traditional periodic tables and the most nonmetallic elements (oxygen, fluorine, chlorine) at the top right. The combination of horizontal and vertical trends in metallic character explains the stair-shaped dividing line between metals and nonmetalsfound on some periodic tables, and the practice of sometimes categorizing several elements adjacent to that line, or elements adjacent to those elements, as metalloids.[47][48]
The lower the values of ionization energy, electronegativity and electron affinity, the more metallic character the element has. Conversely, nonmetallic character increases with higher values of these properties.[45]Given the periodic trends of these three properties, metallic character tends to decrease going across a period (or row) and, with some irregularities (mostly) due to poor screening of the nucleus by d and f electrons, and relativistic effects,[46] tends to increase going down a group (or column or family). Thus, the most metallic elements (such as caesium and francium) are found at the bottom left of traditional periodic tables and the most nonmetallic elements (oxygen, fluorine, chlorine) at the top right. The combination of horizontal and vertical trends in metallic character explains the stair-shaped dividing line between metals and nonmetalsfound on some periodic tables, and the practice of sometimes categorizing several elements adjacent to that line, or elements adjacent to those elements, as metalloids.[47][48]
Linking or bridging groups
From left to right across the four blocks of the long- or 32-column form of the periodic table are a series of linking or bridging groups of elements, located approximately between each block.[49]These groups, like the metalloids, show properties in between, or that are a mixture of, groups to either side. Chemically, the group 3 elements, scandium, yttrium, lanthanum and actinium behave largely like the alkaline earth metals[50] or, more generally, s block metals[51][52] but have some of the physical properties of d block transition metals.[53]Lutetium and lawrencium, at the end of the end of the f block, may constitute another linking or bridging group. Lutetium behaves chemically as a lanthanide but shows a mix of lanthanide and transition metal physical properties.[54][55] Lawrencium, as an analogue of lutetium, would presumably display like characteristics.[n 6] The coinage metals in group 11 (copper, silver, and gold) are chemically capable of acting as either transition metals or main group metals.[58]The volatile group 12 metals, zinc, cadmium and mercury are sometimes regarded as linking the d block to the p block. Notionally they are d block elements but they have few transition metal properties and are more like their p block neighbors in group 13.[59][60] The relatively inert noble gases, in group 18, bridge the most reactive groups of elements in the periodic table—the halogens in group 17 and the alkali metals in group 1.[49]
From left to right across the four blocks of the long- or 32-column form of the periodic table are a series of linking or bridging groups of elements, located approximately between each block.[49]These groups, like the metalloids, show properties in between, or that are a mixture of, groups to either side. Chemically, the group 3 elements, scandium, yttrium, lanthanum and actinium behave largely like the alkaline earth metals[50] or, more generally, s block metals[51][52] but have some of the physical properties of d block transition metals.[53]Lutetium and lawrencium, at the end of the end of the f block, may constitute another linking or bridging group. Lutetium behaves chemically as a lanthanide but shows a mix of lanthanide and transition metal physical properties.[54][55] Lawrencium, as an analogue of lutetium, would presumably display like characteristics.[n 6] The coinage metals in group 11 (copper, silver, and gold) are chemically capable of acting as either transition metals or main group metals.[58]The volatile group 12 metals, zinc, cadmium and mercury are sometimes regarded as linking the d block to the p block. Notionally they are d block elements but they have few transition metal properties and are more like their p block neighbors in group 13.[59][60] The relatively inert noble gases, in group 18, bridge the most reactive groups of elements in the periodic table—the halogens in group 17 and the alkali metals in group 1.[49]
Extremely great
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